An ortho-quinone methide based strategy towards the rubromycin spiroketal family
Author:
Affiliation:
1. Department of Chemistry
2. Queen Mary University of London
3. London E1 4NS
4. United Kingdom
Abstract
A method for the generation/in situhetero-Diels–Alder cycloaddition of a trisubstitutedortho-quinone methide (o-QM) is described.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA17108C
Reference37 articles.
1. Isolation, biological activity and synthesis of benzannulated spiroketal natural products
2. Simple, but Challenging: Recent Developments in the Asymmetric Synthesis of Spiroketals
3. Rubromycins: Structurally Intriguing, Biologically Valuable, Synthetically Challenging Antitumour Antibiotics
4. Isolation, biological activity, biosynthesis and synthetic studies towards the rubromycin family of natural products
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1. Cycloaddition reactions of o-quinone methides with polarized olefins;Russian Chemical Reviews;2021-04-01
2. Rubromycins: A Class of Telomerase Inhibitor Antibiotics Produced by Streptomyces spp.;New and Future Developments in Microbial Biotechnology and Bioengineering;2019
3. Mannich base-connected syntheses mediated by ortho-quinone methides;Beilstein Journal of Organic Chemistry;2018-03-06
4. Synthesis, in vitro antiproliferative activity, antioxidant activity and molecular modeling studies of new carbazole Mannich bases;Medicinal Chemistry Research;2017-05-29
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