Suzuki–Miyaura cross-coupling of amides and esters at room temperature: correlation with barriers to rotation around C–N and C

Suzuki–Miyaura cross-coupling of amides and esters at room temperature: correlation with barriers to rotation around C–N and C–O bonds

Published:2017 Issue:9 Volume:8 Page:6525-6530
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lei Peng¹²³⁴⁵,Meng Guangrong⁶⁷⁸⁹^ORCID,Shi Shicheng⁶⁷⁸⁹^ORCID,Ling Yun¹²³⁴⁵,An Jie¹²³⁴⁵,Szostak Roman⁶¹⁰¹¹¹²^ORCID,Szostak Michal⁶⁷⁸⁹^ORCID

Affiliation:

1. Department of Applied Chemistry

2. College of Science

3. China Agricultural University

4. Beijing 100193

5. China

6. Department of Chemistry

7. Rutgers University

8. Newark

9. USA

10. Wroclaw University

11. Wroclaw

12. Poland

Abstract

We report the first general palladium-catalyzed Suzuki–Miyaura cross-coupling of both common amides and aryl esters through the selective cleavage of the C–N and C–O bonds at ambient temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02692G

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