Selective sodium halide over potassium halide binding and extraction by a heteroditopic halogen bonding [2]catenane-Reference-Cited by-同舟云学术

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Selective sodium halide over potassium halide binding and extraction by a heteroditopic halogen bonding [2]catenane

Published:2024 Issue:32 Volume:15 Page:13074-13081
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tay Hui Min¹^ORCID,Docker Andrew¹²,Hua Carol³^ORCID,Beer Paul D.¹^ORCID

Affiliation:

1. Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK

2. Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK

3. School of Chemistry, The University of Melbourne, Parkville, Victoria, 3010, Australia

Abstract

A heteroditopic [2]catenane is a potent ion-pair receptor for alkali metal halides. It preferentially binds sodium halides over potassium halides, which translates to selective extraction of solid sodium halide salts into organic solvents.

Funder

Clarendon Fund

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC03381G

Reference63 articles.

1. Exploiting the mechanical bond for molecular recognition and sensing of charged species

2. The chemistry of the mechanical bond

3. Chemical consequences of mechanical bonding in catenanes and rotaxanes: isomerism, modification, catalysis and molecular machines for synthesis

4. Development of Pseudorotaxanes and Rotaxanes: From Synthesis to Stimuli-Responsive Motions to Applications

5. Catenanes: Fifty Years of Molecular Links

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