The ligand effect on the oxidative addition of dioxygen to gold(i)–hydride complexes-Reference-Cited by-同舟云学术

The ligand effect on the oxidative addition of dioxygen to gold(i)–hydride complexes

Published:2017 Issue:35 Volume:46 Page:11679-11690
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gaggioli Carlo Alberto¹²³⁴⁵,Belpassi Leonardo⁶⁷⁸^ORCID,Tarantelli Francesco⁶⁷⁸¹⁹^ORCID,Harvey Jeremy N.¹¹⁰¹¹¹²^ORCID,Belanzoni Paola⁶⁷⁸¹⁹^ORCID

Affiliation:

1. Department of Chemistry

2. Chemical Theory Center and Supercomputing Institute

3. University of Minnesota

4. Minneapolis

5. USA

6. Institute of Molecular Science and Technologies (ISTM) – CNR

7. 06123 Perugia

8. Italy

9. Biology and Biotechnology

10. KU Leuven

11. B-3001 Heverlee

12. Belgium

Abstract

The activation energy barriers of the O₂ to [LAuH] oxidative addition, calculated by including spin–orbit coupling (SOC) effects, quantitatively correlate with the σ donation component of the L–AuH bond.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02170D

Reference61 articles.

1. Reactions of a Stable Monomeric Gold(I) Hydride Complex

2. A Thermally Stable Gold(III) Hydride: Synthesis, Reactivity, and Reductive Condensation as a Route to Gold(II) Complexes

3. Hydrides and Iodides of Gold

4. The gold–hydrogen bond, Au–H, and the hydrogen bond to gold, Au⋯H–X

5. Formation and decomposition of alkyl-gold(I) complexes

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