A macrocyclic tetranuclear ZnII complex as a receptor for selective dual fluorescence sensing of F− and AcO−: effect of a macrocyclic ligand

Author:

Chakraborty Tonmoy1234ORCID,Dasgupta Sanchari1234ORCID,Bhattacharyya Arghyadeep1234,Zangrando Ennio5678ORCID,Escudero Daniel191011ORCID,Das Debasis1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Calcutta

3. Kolkata 700009

4. India

5. Department of Chemical and Pharmaceutical Sciences

6. University of Trieste

7. 34127 Trieste

8. Italy

9. KU Leuven

10. B-3001 Leuven

11. Belgium

Abstract

Fluorimetric detection of F/AcO with an additional ‘INHIBIT’ logic gate response for F/H+ and AcO/H+ in an aqueous-methanol medium by a 48-membered macrocyclic ZnII-complex DAS has been explored by combined experimental and theoretical study.

Funder

University Grants Commission

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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