Enhanced hydrogen chemisorption and spillover on non-metallic nickel subnanoclusters

Author:

Nishihara Hirotomo1234ORCID,Ohtake Fumihide1234,Castro-Muñiz Alberto12345ORCID,Itoi Hiroyuki67894ORCID,Ito Masashi101112134,Hayasaka Yuuichiroh14234,Maruyama Jun1516174ORCID,Kondo Junko N.1819204ORCID,Osuga Ryota1819204,Kyotani Takashi1234ORCID

Affiliation:

1. Institute of Multidisciplinary Research for Advanced Materials

2. Tohoku University

3. Sendai

4. Japan

5. Instituto Nacional del Carbón

6. Department of Applied Chemistry

7. Faculty of Engineering

8. Aichi Institute of Technology

9. Toyota

10. Advanced Materials Laboratory

11. Research Division

12. Nissan Motor Co., Ltd

13. Yokosuka

14. The Electron Microscopy Center

15. Research Division of Environmental Technology

16. Osaka Research Institute of Industrial Science and Technology

17. Osaka

18. Institute for Innovative Research

19. Tokyo Institute of Technology

20. Yokohama 226-8503

Abstract

Thermal decomposition of nickelocene loaded onto zeolite-templated carbon (ZTC) yields very fine Ni nanoparticles including subnanoclusters which are in a unique oxidized state and exhibit high activity to H2 chemisorption and the following spillover under ambient conditions.

Funder

New Energy and Industrial Technology Development Organization

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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