The polyhedral nature of selenium-catalysed reactions: Se(iv) species instead of Se(vi) species make the difference in the on water selenium-mediated oxidation of arylamines-Reference-Cited by-同舟云学术

The polyhedral nature of selenium-catalysed reactions: Se(iv) species instead of Se(vi) species make the difference in the on water selenium-mediated oxidation of arylamines

Published:2021 Issue:15 Volume:23 Page:5680-5686
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Tanini Damiano¹²³⁴^ORCID,Dalia Camilla¹²³⁴,Capperucci Antonella¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry “Ugo Schiff”

2. University of Florence

3. Sesto Fiorentino

4. Italy

Abstract

Selenium-mediated on water oxidation of arylamines with H₂O₂ is reported. Nitroarenes or azoxyarenes are selectively achieved by switching the selenium catalyst. Mechanistic analysis and ⁷⁷Se NMR studies highlighted the key role of Se(iv) species.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D0GC04322B

Reference50 articles.

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