Fast detection and structural identification of carbocations on zeolites by dynamic nuclear polarization enhanced solid-state NMR

Author:

Xiao Dong12345ORCID,Xu Shutao67234ORCID,Brownbill Nick J.891011,Paul Subhradip1213141511ORCID,Chen Li-Hua1617185ORCID,Pawsey Shane192021,Aussenac Fabien222324,Su Bao-Lian161718525ORCID,Han Xiuwen12345,Bao Xinhe12345ORCID,Liu Zhongmin12345,Blanc Frédéric89101126ORCID

Affiliation:

1. State Key Laboratory of Catalysis

2. Dalian Institute of Chemical Physics

3. Chinese Academy of Sciences

4. Dalian 116023

5. China

6. National Engineering Laboratory for Methanol to Olefins

7. Dalian National Laboratory for Clean Energy

8. Department of Chemistry

9. University of Liverpool

10. Liverpool

11. UK

12. DNP MAS NMR Facility

13. Sir Peter Mansfield Imaging Centre

14. University of Nottingham

15. Nottingham NG7 2RD

16. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing

17. Wuhan University of Technology

18. Wuhan

19. Bruker BioSpin Corporation

20. Billerica

21. USA

22. Bruker BioSpin

23. 67166 Wissembourg Cedex

24. France

25. CMI (Laboratory of Inorganic Materials Chemistry)

26. Stephenson Institute for Renewable Energy

Abstract

A fast NMR data acquisition strategy is explored to detect and characterize carbocations on solid zeolites.

Funder

National Natural Science Foundation of China

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Engineering and Physical Sciences Research Council

BP

University of Liverpool

Dalian Institute of Chemical Physics

University of Nottingham

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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