High-voltage deprotonation of layered-type materials as a newly identified cause of electrode degradation-Reference-Cited by-同舟云学术

High-voltage deprotonation of layered-type materials as a newly identified cause of electrode degradation

Published:2023 Issue:6 Volume:11 Page:3018-3027
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Yang Junghoon¹²,Park Sungwon³,Lee Sungsik⁴,Kim Jungpil²^ORCID,Huang Di¹,Gim Jihyeon⁵^ORCID,Lee Eungje⁵^ORCID,Kim Gilseob⁶,Park Kyusung¹,Kang Yong-Mook⁶⁷,Paek Eunsu³,Han Sang-Don¹^ORCID

Affiliation:

1. Materials, Chemical, and Computational Science Directorate, National Renewable Energy Laboratory, Golden, CO 80401, USA

2. Carbon and Light Materials Application R&D Group, Korea Institute of Industrial Technology, Jeonju, 54853, Republic of Korea

3. Department of Chemical & Biomolecular Engineering, Clarkson University, Potsdam, NY 13699, USA

4. X-ray Science Division, Argonne National Laboratory, Lemont, IL 60439, USA

5. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439, USA

6. Department of Materials Science and Engineering, Korea University, Seoul, 02841, Republic of Korea

7. KU-KIST Graduate School of Converging Science and Technology, Korea University, Seoul, 02841, Republic of Korea

Abstract

Herein, we report the transition metal dependent deprotonation of layered type materials during their high voltage (>4.5 V vs. Li/Li+) operation as a potential degradation cause in an electrochemical system.

Funder

U.S. Department of Energy

National Research Foundation of Korea

Korea Institute of Industrial Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D2TA07496F

Reference57 articles.

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