Photocurrent of BiVO4 is limited by surface recombination, not surface catalysis
Author:
Affiliation:
1. Helmholtz-Zentrum Berlin für Materialien und Energie GmbH
2. Institute for Solar Fuels
3. 14109 Berlin
4. Germany
5. Department of Chemistry
6. University of Bath
7. Bath BA2, 7AY
8. UK
Abstract
The main role of a cobalt phosphate catalyst on BiVO4 is to improve the photocurrent by passivating the surface and suppressing recombination.
Funder
Seventh Framework Programme
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC00363C
Reference44 articles.
1. Dynamics of photogenerated holes in undoped BiVO4 photoanodes for solar water oxidation
2. Progress in bismuth vanadate photoanodes for use in solar water oxidation
3. Nanoporous BiVO 4 Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting
4. Efficient suppression of back electron/hole recombination in cobalt phosphate surface-modified undoped bismuth vanadate photoanodes
5. Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO4
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