Solubility and hydrolysis of Tc(iv) in dilute to concentrated KCl solutions: an extended thermodynamic model for Tc4+–H+–K+–Na+–Mg2+–Ca2+–OH−–Cl−–H2O(l) mixed systems
Author:
Affiliation:
1. Institute for Nuclear Waste Disposal
2. Karlsruhe Institute of Technology
3. 76021 Karlsruhe
4. Germany
Abstract
The solubility of Tc(iv) under strongly reducing conditions is investigated in KCl solutions with 1.5 ≤ pHm ≤ 14.5, and an extended thermodynamic model for the system Tc4+–H+–K+–Na+–Mg2+–Ca2+–OH−–Cl−–H2O(l) is provided.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ01816A
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