Structure, conformational properties and matrix photochemistry of S-(tert-butyl)trifluorothioacetate CF3C(O)SC(CH3)3-Reference-Cited by-同舟云学术

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Structure, conformational properties and matrix photochemistry of S-(tert-butyl)trifluorothioacetate CF3C(O)SC(CH3)3

Published:2020 Issue:34 Volume:44 Page:14568-14577
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Cayón Vanina M.¹²³⁴⁵^ORCID,Erben Mauricio F.¹²³⁴⁵^ORCID,Romano Rosana M.¹²³⁴⁵^ORCID,Stammler Hans-Georg⁶⁷⁸⁹,Mitzel Norbert W.⁶⁷⁸⁹^ORCID,Della Védova Carlos O.¹²³⁴⁵^ORCID

Affiliation:

1. CEQUINOR (UNLP-CONICET, CCT-La Plata, associated with CIC)

2. Departamento de Química

3. Facultad de Ciencias Exactas

4. Universidad Nacional de La Plata

5. Buenos Aires

6. Universität Bielefeld

7. Lehrstuhl für Anorganische Chemie und Strukturchemie

8. 33615 Bielefeld

9. Germany

Abstract

CF₃C(O)SC(CH₃)₃ species adopts a synperiplanar conformation with C_s symmetry. After UV-visible broadband light irradiation in matrix conditions CF₃C(O)SC(CH₃)₃ photoevolves to CF₃SC(CH₃)₃ and CO.

Funder

Universidad Nacional de La Plata

Agencia Nacional de Promoción Científica y Tecnológica

Comisión de Investigaciones Científicas

Consejo Nacional de Investigaciones Científicas y Técnicas

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ03173A

Reference40 articles.

1. Enzymatic versus spontaneousS-methyl thioester synthesis inGeotrichum candidum

2. Production of volatile compounds by cheese-ripening yeasts: requirement for a methanethiol donor for S -methyl thioacetate synthesis by Kluyveromyces lactis

3. Alkaline hydrolysis and nuclear magnetic resonance spectra of some thiol esters

4. Understanding the Relative Acyl-Transfer Reactivity of Oxoesters and Thioesters: Computational Analysis of Transition State Delocalization Effects

5. Computational Studies of the Aminolysis of Oxoesters and Thioesters in Aqueous Solution

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3. Spectroscopic and structural studies on phenyl and pentafluorophenyl trifluorothioacetate, and pentafluorophenyl trifluoroacetate, CF₃C(O)SC₆H₅, CF₃C(O)SC₆F₅ and CF₃C(O)OC₆F₅;Physical Chemistry Chemical Physics;2023

4. Synthesis, characterization and gas phase conformational properties of chlorodifluoroacetylsulfenyl chloride, CF2ClC(O)SCl;Journal of Molecular Structure;2022-11

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