Excited states and spin–orbit coupling in chalcogen substituted perylene diimides and their radical anions-Reference-Cited by-同舟云学术

Excited states and spin–orbit coupling in chalcogen substituted perylene diimides and their radical anions

Published:2022 Issue:42 Volume:24 Page:26254-26268
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Mentzel Paul¹,Holzapfel Marco¹,Schmiedel Alexander¹,Krummenacher Ivo²³,Braunschweig Holger²³^ORCID,Wodyński Artur⁴,Kaupp Martin⁴^ORCID,Würthner Frank¹⁵^ORCID,Lambert Christoph¹⁵^ORCID

Affiliation:

1. Institut für Organische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

2. Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

3. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

4. Technische Universität Berlin, Institut für Chemie, Theoretische Chemie/Quantenchemie, Sekr. C7, Strasse des 17. Juni 135, 10623 Berlin, Germany

5. Center for Nanosystems Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

Abstract

A novel series of chalcogen bay-substituted perylene diimides show increasing SOC, which was investigated in detail via (time-resolved) optical spectroscopy, (spectro)electrochemistry, EPR spectroscopy and TD-DFT calculations.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP02723B

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