Catalytic enantioselective bromohydroxylation of aryl olefins with flexible functionalities
Author:
Affiliation:
1. Beijing National Laboratory for Molecular Sciences
2. CAS Key Laboratory of Molecular Recognition and Function
3. Institute of Chemistry
4. Chinese Academy of Sciences
5. Beijing 100190
Abstract
A highly enantioselective bromohydroxylation of aryl olefins with flexible functionalities has been achieved with (DHQD)2PHAL as a catalyst and H2O as a nucleophile, giving a variety of optically active bromohydrins with up to 98% ee.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/QO/C6QO00636A
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