Synthesis and characterization of N-heterocyclic carbene–M⋯OEt2 complexes (M = Cu, Ag, Au). Analysis of solvated auxiliary-ligand free [(NHC)M]+ species-Reference-Cited by-同舟云学术

Synthesis and characterization of N-heterocyclic carbene–M⋯OEt2 complexes (M = Cu, Ag, Au). Analysis of solvated auxiliary-ligand free [(NHC)M]+ species

Published:2021 Issue:2 Volume:23 Page:1577-1583
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Muñoz-Castro Alvaro¹²³⁴⁵^ORCID,Wang Guocang⁶⁷⁸⁹,Ponduru Tharun Teja⁶⁷⁸⁹^ORCID,Dias H. V. Rasika⁶⁷⁸⁹^ORCID

Affiliation:

1. Grupo de Química Inorgánica y Materiales Moleculares

2. Facultad de Ingeniería

3. Universidad Autonoma de Chile

4. El Llano Subercaseaux 2801

5. Santiago

6. Department of Chemistry and Biochemistry

7. The University of Texas at Arlington

8. Arlington

9. USA

Abstract

We report the synthesis, characterization and computational analysis of coinage metal-ether and related –OH₂ complexes supported by N-heterocyclic carbenes (NHC), SIPr and ^Et2CAAC.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP05222A

Reference87 articles.

1. An overview of N-heterocyclic carbenes

2. N-Heterocyclic Carbenes in Late Transition Metal Catalysis