Can we trust kinetic methods of thermal analysis?-Reference-Cited by-同舟云学术

Can we trust kinetic methods of thermal analysis?

Published:2020 Issue:3 Volume:145 Page:745-749
ISSN:0003-2654
Container-title:The Analyst
language:en
Short-container-title:Analyst

Author:

Skrdla Peter J.¹²³^ORCID

Affiliation:

1. GlaxoSmithKline

2. Collegeville

3. USA

Abstract

Solid-state reactions/phase transformations where the activation energy changes with the extent of conversion, e.g. multi-step or dispersive kinetic processes, cannot be reliably treated using current thermal methods under non-isothermal conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrochemistry,Spectroscopy,Environmental Chemistry,Biochemistry,Analytical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/AN/C9AN01477B

Reference10 articles.

1. Is the science of thermal analysis kinetics based on solid foundations?

2. ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data

3. ICTAC Kinetics Committee recommendations for collecting experimental thermal analysis data for kinetic computations

4. A time to search: finding the meaning of variable activation energy

5. Dispersive kinetic models predict variation of the activation energy with extent of conversion observed experimentally in isoconversional data

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