The formyloxyl radical: electrophilicity, C–H bond activation and anti-Markovnikov selectivity in the oxidation of aliphatic alkenes-Reference-Cited by-同舟云学术

The formyloxyl radical: electrophilicity, C–H bond activation and anti-Markovnikov selectivity in the oxidation of aliphatic alkenes

Published:2020 Issue:42 Volume:11 Page:11584-11591
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Somekh Miriam¹²³⁴,Iron Mark A.⁵⁶²³⁴^ORCID,Khenkin Alexander M.¹²³⁴,Neumann Ronny¹²³⁴^ORCID

Affiliation:

1. Department of Organic Chemistry

2. Weizmann Institute of Science

3. Rehovot

4. Israel

5. Computational Chemistry Unit

6. Department of Chemical Research Support

Abstract

The formyloxyl radical, formed electrochemically, is electrophilic, yields anti-Markovnikov oxidation products from alkenes, and is effective for C–H bond activation.

Funder

Israel Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04936K

Reference70 articles.

1. The Radical Pair Yield of Ionizing Radiation in Aqueous Solutions of Formic Acid

2. Radiation chemistry of aqueous solutions containing both ferrous ion and carbon dioxide

3. Fluorescence yields from photodissociative excitation of formic acid, methyl formate, and acetic acid in the vacuum-ultraviolet region

4. Study of HCO2and DCO2by negative ion photoelectron spectroscopy

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