The formyloxyl radical: electrophilicity, C–H bond activation and anti-Markovnikov selectivity in the oxidation of aliphatic alkenes
Author:
Affiliation:
1. Department of Organic Chemistry
2. Weizmann Institute of Science
3. Rehovot
4. Israel
5. Computational Chemistry Unit
6. Department of Chemical Research Support
Abstract
The formyloxyl radical, formed electrochemically, is electrophilic, yields anti-Markovnikov oxidation products from alkenes, and is effective for C–H bond activation.
Funder
Israel Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04936K
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4. Study of HCO2and DCO2by negative ion photoelectron spectroscopy
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1. Br−/BrO−-mediated highly efficient photoelectrochemical epoxidation of alkenes on α-Fe2O3;Nature Communications;2023-04-07
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