Slow magnetic relaxation for cobalt(<scp>ii</scp>) complexes in axial bipyramidal environment: an <i>S</i> = 1/2 spin case-Reference-Cited by-同舟云学术

Slow magnetic relaxation for cobalt(ii) complexes in axial bipyramidal environment: an S = 1/2 spin case

Published:2022 Issue:23 Volume:51 Page:8986-8993
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pilichos Evangelos¹,Font-Bardia Mercè²,Cano Joan³^ORCID,Escuer Albert¹^ORCID,Mayans Júlia¹^ORCID

Affiliation:

1. Departament de Química Inorgànica i Orgànica, Secció Inorgànica and Institute of Nanoscience (IN2UB) and Nanotecnology, Universitat de Barcelona, Marti i Franques 1-11, Barcelona-08028, Spain

2. Departament de Mineralogia, Cristal lografia i Dipòsits Minerals and Unitat de Difracció de R-X, Centre Científic i Tecnològic de la Universitat de Barcelona (CCiTUB), Universitat de Barcelona, Solé i Sabarís 1-3, 08028 Barcelona, Spain

3. Instituto de Ciencia Molecular (ICMol), Universitat de València, 46980 Paterna, València, Spain

Abstract

The slow magnetic relaxation for CoII cations in an unusual axial bipyramidal environment and psudo-spin 1/2 has been explored, showing a Direct plus Raman relaxation mechanism.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00880G

Reference39 articles.

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2. Magnetic bistability in a metal-ion cluster

3. Hexanuclear Manganese(III) Single-Molecule Magnets

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5. Chiroptical and magnetic properties of star-shaped FeIII4 complexes from chiral Schiff bases. Structural and magnetic correlations based on continuous shape measures

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