Synthesis and coordination behaviour of aluminate-based quinolyl ligands

Author:

Waters Jessica E.1,Hanf Schirin2ORCID,Rincón-Nocito Marina1,Bond Andrew D.1ORCID,García-Rodríguez Raul3ORCID,Wright Dominic S.1ORCID,Colebatch Annie L.4ORCID

Affiliation:

1. Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK

2. Karlsruhe Institut für Technologie (KIT), 76131 Karlsruhe, Baden-Württemberg, Germany

3. GIR MIOMeT-IU Cinquima-Química, Inorgunica Facultad de Ciencias, Universidad de Valladolid, Campus Miguel Delibes, 47011 Valladolid, Spain

4. Research School of Chemistry, The Australian National University, Canberra, ACT 2601, Australia

Abstract

The effects of moving the donor N-atom from the 2-position to the more remote position in (8-quinolyl)aluminates have been investigated by solid-state structural studies and DFT calculations, with large differences in Li+ coordination being found.

Funder

Leverhulme Trust

Australian Research Council

Bundesministerium für Bildung und Forschung

Deutsche Forschungsgemeinschaft

Ministerio de Economía y Competitividad

European Social Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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