Ultrathin Rh nanosheets as a highly efficient bifunctional electrocatalyst for isopropanol-assisted overall water splitting

Author:

Zhao Yue12345,Xing Shihui12345,Meng Xinying12345,Zeng Jinghui12345,Yin Shibin678910,Li Xifei11121310,Chen Yu12345ORCID

Affiliation:

1. Key Laboratory of Macromolecular Science of Shaanxi Province

2. Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education)

3. Shaanxi Key Laboratory for Advanced Energy Devices

4. School of Materials Science and Engineering

5. Shaanxi Normal University

6. Collaborative Innovation Center of Sustainable Energy Materials

7. Guangxi Key Laboratory of Electrochemical Energy Materials

8. Guangxi University

9. Nanning 530004

10. P. R. China

11. Institute of Advanced Electrochemical Energy

12. Xi'an University of Technology

13. Xi'an 710048

Abstract

In this work, we report energy-saving H2 production by replacing the oxygen evolution reaction with the thermodynamic favorable isopropanol oxidation reaction (IOR) based on a bifunctional ultrathin Rh nanosheets electrocatalyst (Rh-NSs), which only requires the voltage of 0.4 V to achieve the H2 and acetone co-production.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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