β-Perfluoroalkyl-substituted pyrrole as an anion-responsive π-electronic system through a single NH moiety

Author:

Haketa Yohei12345,Takasago Ryota12345,Maeda Hiromitsu12345

Affiliation:

1. Department of Applied Chemistry

2. College of Life Sciences

3. Ritsumeikan University

4. Kusatsu 525-8577

5. Japan

Abstract

A pyrrole derivative possessing two perfluorohexyl (C6F13) chains at the β-positions was synthesized. The significant electron-withdrawing properties of the β-perfluoroalkyl chains induced fascinating anion-binding behaviour.

Funder

Ministry of Education, Culture, Sports, Science, and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference34 articles.

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2. J. L. Sessler , P. A.Gale and W.-S.Cho, Anion Receptor Chemistry, RSC, Cambridge, 2006

3. Anion Recognition in Supramolecular Chemistry, Topics in Heterocyclic Chemistry, ed. P. A. Gale and W. Dehaen, Springer-Verlag, Berlin, 2010, vol. 24, pp. 1–413

4. Pyrrolic and polypyrrolic anion binding agents

5. Recent progress in research on anion-responsive pyrrole-based π-conjugated acyclic molecules

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