Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia-Reference-Cited by-同舟云学术

Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia

Published:2015 Issue:62 Volume:51 Page:12419-12422
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Liliang¹²³⁴⁵,Kong Lingbing¹²³⁴⁵,Li Yongxin⁶⁷⁴⁵,Ganguly Rakesh⁶⁷⁴⁵,Kinjo Rei¹²³⁴⁵

Affiliation:

1. Division of Chemistry and Biological Chemistry

2. School of Physical and Mathematical Sciences

3. Nanyang Technological University

4. Singapore 637371

5. Singapore

6. NTU-CBC Crystallography Facility

7. Nanyang Technological University, Nanyang Link 21

Abstract

Gold-catalyzed hydroimination of terminal alkynes, giving rise to anti-Markovnikov adducts concomitant with unstable Markovnikov adducts is described.

Funder

Science and Engineering Research Council, Agency for Science, Technology and Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04091D

Reference48 articles.

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3. Early Transition Metal (Group 3–5, Lanthanides and Actinides) and Main Group Metal (Group 1, 2, and 13) Catalyzed Hydroamination

4. J. F. Hartwig , Organotransition Metal Chemistry, University Science Books, Mill Valley, CA, 2010, ch. 16.5, p.700

5. Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

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