Ruthenium-catalyzed formal sp3 C–H activation of allylsilanes/esters with olefins: efficient access to functionalized 1,3-dienes-Reference-Cited by-同舟云学术

Ruthenium-catalyzed formal sp3 C–H activation of allylsilanes/esters with olefins: efficient access to functionalized 1,3-dienes

Published:2021 Issue:12 Volume:12 Page:4367-4372
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Dethe Dattatraya H.¹²³⁴^ORCID,Beeralingappa Nagabhushana C.¹²³⁴,Das Saikat¹²³⁴,Nirpal Appasaheb K.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kanpur

3. Kanpur

4. India

Abstract

Ru-catalysed oxidative coupling of allylsilanes and allyl esters with activated olefins has been developed via isomerization followed by C(allyl)–H activation providing efficient access to stereodefined 1,3-dienes in excellent yields.

Funder

University Grants Commission

Indian Institute of Technology Kanpur

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06845D

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4. Regioselective Hydroacylation of 1,3-Dienes by Cobalt Catalysis

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