Silyl diol ester as a new selectivity control agent in MgCl2-supported Ziegler–Natta systems for propylene polymerization: catalyst structure and polymer properties
Author:
Affiliation:
1. Department of Polymerization Engineering
2. Iran Polymer and Petrochemical Institute
3. Tehran
4. Iran
Abstract
In this study, bis(benzoyloxy)dimethylsilane (SDE) was developed as a non-phthalate selectivity control agent (internal donor (ID) and external donor (ED)) in MgCl2-supported Ziegler–Natta (ZN) systems for polypropylene polymerization.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA00715F
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1. Molecular simulation of selective coordination for various silyl ester Lewis base donors with MgCl2 in Ziegler–Natta catalysis;Molecular Simulation;2023-07-24
2. Effect of adduct synthesis parameters on the ethylene polymerization kinetics of Ziegler Natta catalysts;Journal of Applied Polymer Science;2023-05-04
3. Synthesis of Bis(methoxymethyl)silanes and Their Application in MgCl2-Supported Ziegler–Natta Propylene Polymerization as External Donors;Industrial & Engineering Chemistry Research;2022-11-02
4. Propylene Polymerization Performance with Ziegler-Natta Catalysts Combined with U-Donor and T01 Donor as External Donor;Catalysts;2022-08-05
5. Molecular-level insights into adsorption of a novel silyl ester donor on essential MgCl2 facets of supported Ziegler–Natta catalysts;Journal of Physics and Chemistry of Solids;2021-12
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