Effect of oxygen deficiency on the excited state kinetics of WO3 and implications for photocatalysis

Author:

Sachs Michael1234ORCID,Park Ji-Sang52346ORCID,Pastor Ernest1234ORCID,Kafizas Andreas12347ORCID,Wilson Anna A.1234,Francàs Laia1234ORCID,Gul Sheraz891011,Ling Min11234ORCID,Blackman Chris11234ORCID,Yano Junko891011,Walsh Aron52346ORCID,Durrant James R.1234ORCID

Affiliation:

1. Department of Chemistry

2. Imperial College London

3. London

4. UK

5. Department of Materials

6. Department of Materials Science and Engineering

7. The Grantham Institute

8. Molecular Biophysics and Integrated Bioimaging Division

9. Lawrence Berkeley National Laboratory

10. Berkeley

11. USA

12. University College London

Abstract

Using WO3 as a model material, we investigate how different oxygen vacancy concentrations affect trapping of photogenerated charges and photocatalytic reactions in metal oxides.

Funder

Engineering and Physical Sciences Research Council

U.S. Department of Energy

Royal Society

Imperial College London

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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