Highly tunable fluorinated trispyrazolylborates [HB(3-CF3-5-{4-RPh}pz)3]− (R = NO2, CF3, Cl, F, H, OMe and NMe2) and their copper(i) complexes-Reference-Cited by-同舟云学术

Highly tunable fluorinated trispyrazolylborates [HB(3-CF3-5-{4-RPh}pz)3]− (R = NO2, CF3, Cl, F, H, OMe and NMe2) and their copper(i) complexes

Published:2015 Issue:48 Volume:44 Page:21109-21123
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

van Dijkman Thomas F.¹²³⁴,Siegler Maxime A.⁵⁶⁷⁸,Bouwman Elisabeth¹²³⁴^ORCID

Affiliation:

1. Leiden Institute of Chemistry

2. Leiden University

3. Leiden

4. the Netherlands

5. Department of Chemistry

6. Johns Hopkins University

7. Baltimore

8. USA

Abstract

A spectroscopic series of fluorinated trispyrazolylborate ligands was used to make copper(i) complexes with carbon monoxide and ethene. The tunable ligands induce clear trends in infrared and NMR spectra of the copper compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT04006J

Reference38 articles.

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