Ionic liquid surfactants as multitasking micellar catalysts for epoxidations in water-Reference-Cited by-同舟云学术

Ionic liquid surfactants as multitasking micellar catalysts for epoxidations in water

Published:2020 Issue:13 Volume:10 Page:4448-4457
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Schmidt Fabian¹²³⁴⁵,Zehner Bastian⁶⁷⁸⁵,Korth Wolfgang⁶⁷⁸⁵,Jess Andreas⁶⁷⁸⁵,Cokoja Mirza¹²³⁴⁵^ORCID

Affiliation:

1. Chair of Inorganic and Metal-Organic Chemistry

2. Faculty of Chemistry and Catalysis Research Center

3. Technical University of Munich

4. D-85747 Garching bei München

5. Germany

6. Chair of Chemical Engineering

7. Faculty of Engineering Science

8. D-95447 Bayreuth

Abstract

Surface-active imidazolium tungstate ILs are multitask epoxidation catalysts in water using H₂O₂ as oxidant. The micelles solubilize olefins in the aqueous phase and catalyze the epoxidation. Organophosphonic acids greatly increase the reaction rate.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY00673D

Reference46 articles.

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2. Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant

3. Epoxidation of olefins with homogeneous catalysts – quo vadis?