Halogen bonding between metal-bound I3− and unbound I2: the trapped I2⋯I3− intermediate in the controlled assembly of copper(<scp>i</scp>)-based polyiodides-Reference-Cited by-同舟云学术

Halogen bonding between metal-bound I₃⁻ and unbound I₂: the trapped I₂⋯I₃⁻ intermediate in the controlled assembly of copper(i)-based polyiodides

Published:2023 Issue:5 Volume:10 Page:1522-1533
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Kinzhalov Mikhail A.¹²^ORCID,Ivanov Daniil M.¹²^ORCID,Shishkina Anastasia V.³^ORCID,Melekhova Anna A.¹^ORCID,Suslonov Vitalii V.¹²^ORCID,Frontera Antonio⁴^ORCID,Kukushkin Vadim Yu.¹⁵^ORCID,Bokach Nadezhda A.¹²^ORCID

Affiliation:

1. St Petersburg State University, Universitetskaya Nab. 7/9, Saint Petersburg, 199034, Russian Federation

2. Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, 634050 Tomsk, Russian Federation

3. Department of Physics and Engineering Environmental Protection, Northern (Arctic) Federal University, Arkhangelsk, 163001, Russian Federation

4. Department of Chemistry, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain

5. Institute of Chemistry and Pharmaceutical Technologies, Altai State University, Barnaul, 656049, Russian Federation

Abstract

The identification of halogen bonded-intermediates is key to understanding the precise mechanism for the generation of I5− (and I82−) ligands from I2 and metal-coordinated I3−.

Funder

Agencia Estatal de Investigación

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D2QI02634A

Reference70 articles.

1. Synthesis, Structure, and Bonding in Polyiodide and Metal Iodide−Iodine Systems

2. Recent Discoveries of Polyhalogen Anions - from Bromine to Fluorine