Hypervalent diorganoantimony(iii) fluorides via diorganoantimony(iii) cations – a general method of synthesis-Reference-Cited by-同舟云学术

Hypervalent diorganoantimony(iii) fluorides via diorganoantimony(iii) cations – a general method of synthesis

Published:2015 Issue:121 Volume:5 Page:99832-99840
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Preda Ana Maria¹²³⁴⁵,Raţ Ciprian I.¹²³⁴⁵,Silvestru Cristian¹²³⁴⁵,Lang Heinrich⁶⁷⁸⁹¹⁰,Rüffer Tobias⁶⁷⁸⁹¹⁰,Mehring Michael⁶⁷¹¹⁹¹⁰

Affiliation:

1. Departamentul de Chimie

2. Centrul de Chimie Supramoleculară Organică şi Organometalică (CCSOOM)

3. Facultatea de Chimie şi Inginerie Chimică

4. Universitatea Babeş-Bolyai

5. 400028 Cluj-Napoca

6. Institut für Chemie

7. Technische Universität Chemnitz

8. Anorganische Chemie

9. D-09111 Chemnitz

10. Germany

11. Koordinationschemie

Abstract

A new general synthesis method for hypervalent diorganoantimony(iii) fluorides with pendant arm ligands is based on treatment with [Bu₄N]F·3H₂O of cationic species e.g. [{2-(2′,6′-ⁱPr₂C₆H₃NCH)C₆H₄}₂Sb]⁺[PF₆]⁻ or [{2-(Me₂NCH₂)C₆H₄}PhSb]⁺[SbF₆]⁻.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA21788A

Reference42 articles.

1. Le fluorure de tétraphénylstibonium. Mesures dans l'ultra-violet

2. Fluoride Anion Chelation by a Bidentate Stibonium–Borane Lewis Acid

3. Sensing of Aqueous Fluoride Anions by Cationic Stibine-Palladium Complexes

4. Stibonium Ions for the Fluorescence Turn-On Sensing of F– in Drinking Water at Parts per Million Concentrations

5. Anion-Controlled Switching of an X Ligand into a Z Ligand: Coordination Non-innocence of a Stiboranyl Ligand

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