Unusual triplet–triplet annihilation in a 3D copper(i) chloride coordination polymer-Reference-Cited by-同舟云学术

Unusual triplet–triplet annihilation in a 3D copper(i) chloride coordination polymer

Published:2019 Issue:30 Volume:21 Page:16538-16548
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Schlachter Adrien¹²³⁴⁵^ORCID,Bonnot Antoine¹²³⁴⁵,Fortin Daniel¹²³⁴⁵,Karsenti Paul-Ludovic¹²³⁴⁵,Knorr Michael⁶⁷⁸⁹^ORCID,Harvey Pierre D.¹²³⁴⁵^ORCID

Affiliation:

1. Département de chimie

2. Université de Sherbrooke

3. Sherbrooke

4. Québec

5. Canada

6. Institut UTINAM UMR CNRS 6213

7. Université Bourgogne Franche-Comté

8. 25030 Besançon

9. France

Abstract

[Cu₂Cl₂(EtS(CH₂)₄SEt)₄]_n exhibits ultrafast Dexter driven triplet–triplet annihilation at 298 K (k_Q = 1.3 × 10¹⁰ s⁻¹) but a significantly slower one at 77 K (by 20 folds), despite large contraction of the unit cell. This process is explained by a large activation barrier.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP02891A

Reference75 articles.

1. Circularly Polarized Luminescence from a Pyrene-Cyclodextrin Supra-Dendron

2. Nonlinear optical properties, upconversion and lasing in metal–organic frameworks

3. Designing next generation of photon upconversion: Recent advances in organic triplet-triplet annihilation upconversion nanoparticles

4. Bioimaging and biodetection assisted with TTA-UC materials

5. M. Scholz and R.Dedic , Singlet Oxygen: Applications in Biosciences and Nanosciences , 2016 , vol. 2, pp. 63–81

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