A novel dynamic pseudo[1]rotaxane based on a mono-biotin-functionalized pillar[5]arene-Reference-Cited by-同舟云学术

A novel dynamic pseudo[1]rotaxane based on a mono-biotin-functionalized pillar[5]arene

Published:2015 Issue:9 Volume:2 Page:1013-1017
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wu Xuan¹²³⁴⁵,Ni Mengfei¹²³⁴⁵,Xia Wei¹²³⁴⁵,Hu Xiao-Yu¹²³⁴⁵,Wang Leyong¹²³⁴⁵

Affiliation:

1. Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences

2. School of Chemistry and Chemical Engineering

3. Nanjing University

4. Nanjing

5. China

Abstract

A stable pillar[5]arene-based pseudo[1]rotaxane P1′ was synthesized by the click reaction, which exhibited a dynamic slow disassembly process upon adding a strong-polar solvent or competitive guest. Moreover, this dynamic behavior might be used as a switch to turn on or off the bioactivity of the biotin moiety in aqueous solution.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/QO/C5QO00159E

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