Bi-Blatter diradicals: conformation and substituent dependent high-spin materials

Author:

Pomikło Dominika1ORCID,Szamweber Patrycja1ORCID,Pietrzak Anna2ORCID,Kaszyński Piotr134ORCID

Affiliation:

1. Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90-363 Łódź, Poland

2. Faculty of Chemistry, Łódź University of Technology, 90-924 Łódź, Poland

3. Faculty of Chemistry, University of Łódź, 91-403 Łódź, Poland

4. Organic Materials Research Group, Department of Chemistry, Middle Tennessee State University, Murfreesboro, TN 37132, USA

Abstract

A class of unusual triplet diradicals: two stable conformers in two regioisomers have different ΔES–T, which define their net magnetic behavior.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Reference52 articles.

1. From Stable Radicals to Thermally Robust High-Spin Diradicals and Triradicals

2. High-Spin Organic Molecules

3. M.Baumgarten , High-spin organic molecules , in World Scientific Reference on Spin in Organics , ed. J. S. Miller , Materials and Energy, vol. 10, World Scientific , 2018 , vol. 4, pp. 1–93

4. Persistent and Stable Organic Radicals: Design, Synthesis, and Applications

5. Playing with organic radicals as building blocks for functional molecular materials

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