The nature of [N–Cl–N]+and [N–F–N]+halogen bonds in solution-Reference-Cited by-同舟云学术

The nature of [N–Cl–N]+and [N–F–N]+halogen bonds in solution

Published:2014 Issue:8 Volume:5 Page:3226-3233
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Karim Alavi¹²³,Reitti Marcus¹²³,Carlsson Anna-Carin C.¹²³,Gräfenstein Jürgen¹²³,Erdélyi Máté¹²³

Affiliation:

1. Department of Chemistry and Molecular Biology

2. University of Gothenburg

3. SE-412 96 Gothenburg, Sweden

Abstract

The solution symmetry of [N–Cl–N]⁺and [N–F–N]⁺halogen bonds is discussed, in comparison to the iodine and bromine-centered bonds as well as to the corresponding three-center [N–H–N]⁺hydrogen bond.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01175A

Reference76 articles.

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5. Stable carbonium ions. LXII. Halonium ion formation via neighboring halogen participation: ethylenehalonium, propylenehalonium, and 1,2-dimethylethylenehalonium ions

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