Aminocyclopropenium as a novel hydrogen bonding organocatalyst for cycloaddition of carbon disulfide and epoxide to prepare cyclic dithiocarbonate-Reference-Cited by-同舟云学术

Aminocyclopropenium as a novel hydrogen bonding organocatalyst for cycloaddition of carbon disulfide and epoxide to prepare cyclic dithiocarbonate

Published:2024 Issue:15 Volume:14 Page:10378-10389
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Du Xinru¹,Liu Ziqi²,Li Zhenjiang²^ORCID,Yuan Xin²,Li Chunyu²,Zhang Min²,Zhang Zhihao²,Hu Xin¹^ORCID,Guo Kai²^ORCID

Affiliation:

1. College of Materials Science and Engineering, Nanjing Tech University, 30 Puzhu Road South, Nanjing 211816, China

2. State Key Laboratory Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, 30 Puzhu Road South, Nanjing 211816, China

Abstract

The hybrid H-bond donor cyclopropenium was vital in activating the epoxide and stabilizing the anion intermediate.

Funder

National Natural Science Foundation of China

Jiangsu National Synergistic Innovation Center for Advanced Materials

Priority Academic Program Development of Jiangsu Higher Education Institutions

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D4RA00937A

Reference61 articles.

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4. A Phosphonium Ylide as a Ligand for [3 + 2] Coupling Reactions of Epoxides with Heterocumulenes under Mild Conditions

5. Titanium(salen)-Catalysed Synthesis of Di- and Trithiocarbonates from Epoxides and Carbon Disulfide