A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [B3O3F4(OH)]2−-Reference-Cited by-同舟云学术

A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [B₃O₃F₄(OH)]²⁻

Published:2024 Issue:35 Volume:48 Page:15281-15286
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Ouyang Tao¹²,Chen Xu¹²,Chen Shanshan²,Li Yanqiang²,Shang Xiaoying²,Bai Zhiyong²,Jiang Ningtao³,Yan Zhishuo³,Luo Junhua²,Zhao Sangen²^ORCID

Affiliation:

1. College of Chemistry, Fuzhou University, Fuzhou 350116, China

2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

3. Department of Electrical and Computer Engineering, North Dakota State University, Fargo 58102, USA

Abstract

Based on a π-conjugated confinement strategy, we designed and synthesized a deep-UV NLO crystal, K2B3O3F4(OH), exhibiting a moderate birefringence (0.054@550 nm) and deep-UV transparency (<200 nm).

Funder

Natural Science Foundation of Fujian Province

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Youth Innovation Promotion Association of Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ02834A

Reference47 articles.

1. Design and synthesis of an ultraviolet-transparent nonlinear optical crystal Sr2Be2B2O7

2. Linear- and nonlinear-optical properties of a new gadolinium calcium oxoborate crystal, Ca_4GdO(BO_3)_3

3. Physical Properties of a Promising Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F

4. Noncentrosymmetric Rare-Earth Borate Fluoride La₂B₅O₉F₃: A New Ultraviolet Nonlinear Optical Crystal with Enhanced Linear and Nonlinear Performance

5. A Ferroelectric Nonlinear Optical Crystal for Deep‐UV Quasi‐Phase‐Matching