From light to heavy alkali metal tetraphosphonates (M = Li, Na, K, Rb, Cs): cation size-induced structural diversity and water-facilitated proton conductivity-Reference-Cited by-同舟云学术

From light to heavy alkali metal tetraphosphonates (M = Li, Na, K, Rb, Cs): cation size-induced structural diversity and water-facilitated proton conductivity

Published:2018 Issue:47 Volume:20 Page:7648-7658
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Salcedo Inés R.¹²³⁴,Colodrero Rosario M. P.⁵⁶⁷⁸^ORCID,Bazaga-García Montse¹²³⁴^ORCID,Vasileiou Antonia⁹¹⁰¹¹¹²¹³,Papadaki Maria⁹¹⁰¹¹¹²¹³,Olivera-Pastor Pascual¹²³⁴^ORCID,Infantes-Molina Antonia¹²³⁴,Losilla Enrique R.¹²³⁴^ORCID,Mezei Gellert¹⁰¹⁴¹⁵¹⁶^ORCID,Cabeza Aurelio¹²³⁴^ORCID,Demadis Konstantinos D.⁹¹⁰¹¹¹²¹³^ORCID

Affiliation:

1. Departamento de Química Inorgánica

2. Universidad de Málaga

3. Málaga-29071

4. Spain

5. Faculty of Science & Engineering

6. University of Wolverhampton

7. Wolverhampton WV1 1LY

8. UK

9. Crystal Engineering, Growth and Design Laboratory

10. Department of Chemistry

11. University of Crete

12. Crete

13. Greece

14. Western Michigan University

15. Kalamazoo

16. USA

Abstract

A family of alkali metal-based frameworks containing the tetraphosphonate linker hexamethylenediamine-N,N,N′,N′-tetrakis(methylenephosphonic acid), HDTMP, exhibiting rich structural diversity and water-dependent proton conductivity.

Funder

University of Crete

Ministerio de Economía y Competitividad

Junta de Andalucía

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CE/C8CE01351A

Reference69 articles.

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2. Tailored Organic-Inorganic Materials , ed. E. Brunet , J. L. Colón and A. Clearfield , John Wiley & Sons, Inc. , New York, U.S.A. , 2015

3. Extending the Pore Size of Crystalline Metal Phosphonates toward the Mesoporous Regime by Isoreticular Synthesis

4. Structural Transformations and Adsorption of Fuel-Related Gases of a Structurally Responsive Nickel Phosphonate Metal−Organic Framework, Ni-STA-12

5. Metal phosphonate open-framework materials

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