Three-component addition of terminal alkynes, carboxylic acids, and <i>tert</i>-butyl hypochlorite-Reference-Cited by-同舟云学术

Three-component addition of terminal alkynes, carboxylic acids, and tert-butyl hypochlorite

Published:2022 Issue:16 Volume:58 Page:2670-2673
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Xitao¹,Zhang Sheng¹,Li Shihong¹,Feng Xiujuan¹,Yamamoto Yoshinori¹²³^ORCID,Bao Ming¹^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China

2. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan

3. Research Organization of Science and Technology, Ritsumeikan University, Kusatsu, Shiga 525-8577, Japan

Abstract

Three-component addition of terminal alkynes, carboxylic acids, and tert-butyl hypochlorite is developed. This new type of addition proceeds smoothly to produce gem-dichloroalkane derivatives via successive two-time additions under mild conditions.

Funder

National Natural Science Foundation of China

Liaoning Revitalization Talents Program

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC00374K

Reference37 articles.

1. Catalytic Markovnikov and anti-Markovnikov Functionalization of Alkenes and Alkynes: Recent Developments and Trends

2. Transition-Metal-Catalyzed Addition of Heteroatom−Hydrogen Bonds to Alkynes

3. Transition‐Metal‐Catalyzed Hydroarylation Reactions of Alkynes Through Direct Functionalization of C–H Bonds: A Convenient Tool for Organic Synthesis

4. Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions

5. Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes

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