On the nature of bonding in the photochemical addition of two ethylenes: C–C bond formation in the excited state?-Reference-Cited by-同舟云学术

On the nature of bonding in the photochemical addition of two ethylenes: C–C bond formation in the excited state?

Published:2021 Issue:36 Volume:23 Page:20598-20606
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Guerra Cristian¹,Ayarde-Henríquez Leandro¹^ORCID,Duque-Noreña Mario¹,Cárdenas Carlos²³^ORCID,Pérez Patricia¹,Chamorro Eduardo¹^ORCID

Affiliation:

1. Universidad Andres Bello, Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Avenida República 275, 8370146, Santiago, Chile

2. Universidad de Chile, Facultad de Ciencias, Departamento de Física, Avenida Las Palmeras 3425, Santiago, Chile

3. Centro para el Desarrollo de la Nanociencia y la Nanotecnología (CEDENNA), 9170124 Santiago, Chile

Abstract

Abrupt changes in the ELF topology can be associated with bonding events along the [2+2] cycloaddition process. Activation of carbon centers features the excited surface, whereas the C–C bond formation occurs in the ground state.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP03554A

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