Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures

Author:

Gearing Hayden B.1,Söhnel Tilo12ORCID,Young Paul3ORCID,Lisboa Lynn4,Wright L. James1ORCID,Crowley James D.24ORCID,Hartinger Christian G.1ORCID

Affiliation:

1. School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand

2. MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, PO Box 600, Wellington 6140, New Zealand

3. School of Biological Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand

4. Department of Chemistry, University of Otago, PO Box 56, Dunedin 9054, New Zealand

Abstract

Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bond-accepting or -donating properties are reported.

Funder

Marsden Fund

Publisher

Royal Society of Chemistry (RSC)

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