Temperature-dependence of radical-trapping activity of phenoxazine, phenothiazine and their aza-analogues clarifies the way forward for new antioxidant design

Author:

Poon Jia-Fei1ORCID,Farmer Luke A.1ORCID,Haidasz Evan A.1,Pratt Derek A.1ORCID

Affiliation:

1. Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie Pvt., Ottawa, Ontario, K1N 6N5, Canada

Abstract

Studies of potent diarylamine antioxidants illustrate how their high-temperature activity can be limited by direct reaction with O2, and how driving force and barrier to oxidation can be modulated for future antioxidant development.

Funder

Natural Sciences and Engineering Research Council of Canada

Canada Foundation for Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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