Magnetic circular dichroism of UCl6− in the ligand-to-metal charge-transfer spectral region-Reference-Cited by-同舟云学术

Magnetic circular dichroism of UCl6− in the ligand-to-metal charge-transfer spectral region

Published:2017 Issue:26 Volume:19 Page:17300-17313
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Gendron Frédéric¹²³⁴⁵^ORCID,Fleischauer Valerie E.¹⁶⁷⁵,Duignan Thomas J.¹²³⁴⁵^ORCID,Scott Brian L.⁸⁹¹⁰⁵,Löble Matthias W.⁸⁹¹⁰⁵,Cary Samantha K.⁸⁹¹⁰⁵,Kozimor Stosh A.⁸⁹¹⁰⁵^ORCID,Bolvin Hélène¹¹¹²¹³,Neidig Michael L.¹⁶⁷⁵,Autschbach Jochen¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University at Buffalo

3. State University of New York

4. Buffalo

5. USA

6. University of Rochester

7. Rochester

8. Los Alamos National Laboratory

9. Los Alamos

10. New Mexico 87544

11. Laboratoire de Chimie et de Physique Quantiques

12. 31062 Toulouse

13. France

Abstract

We present a combined ab initio theoretical and experimental study of the magnetic circular dichroism (MCD) spectrum of the octahedral UCl₆⁻ complex ion in the UV-Vis spectral region.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP02572F

Reference90 articles.

1. Detailed Spectroscopic and Theoretical Studies on [Fe(EDTA)(O2)]3-: Electronic Structure of the Side-on Ferric−Peroxide Bond and Its Relevance to Reactivity

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3. Magnetic Circular Dichroism Evidence for an Unusual Electronic Structure of a Tetracarbene–Oxoiron(IV) Complex

4. Electronic Structure and Bonding in Iron(II) and Iron(I) Complexes Bearing Bisphosphine Ligands of Relevance to Iron-Catalyzed C–C Cross-Coupling

5. A combined magnetic circular dichroism and density functional theory approach for the elucidation of electronic structure and bonding in three- and four-coordinate iron(ii)–N-heterocyclic carbene complexes

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