Copper-catalysed cross-coupling of alkyl Grignard reagents and propargylic ammonium salts: stereospecific synthesis of allenes-Reference-Cited by-同舟云学术

Copper-catalysed cross-coupling of alkyl Grignard reagents and propargylic ammonium salts: stereospecific synthesis of allenes

Published:2018 Issue:60 Volume:54 Page:8343-8346
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Guisán-Ceinos Manuel¹²³⁴⁵,Martín-Heras Victor¹²³⁴⁵,Soler-Yanes Rita¹²³⁴⁵,Cárdenas Diego J.¹²³⁴⁵^ORCID,Tortosa Mariola¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química Orgánica

2. Facultad de Ciencias

3. Institute for Advanced Research in Chemical Sciences (IAdChem)

4. Universidad Autónoma de Madrid

5. Cantoblanco

Abstract

A robust and convenient method to prepare enantiomerically enriched allenes using propargylic salts is reported. High yields and excellent chirality transfer are observed.

Funder

FP7 Ideas: European Research Council

Secretaría de Estado de Investigación, Desarrollo e Innovación

Universidad Autónoma de Madrid

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC03760D

Reference51 articles.

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3. Transition Metal-Catalyzed/Mediated Reaction of Allenes with a Nucleophilic Functionality Connected to the α-Carbon Atom

4. Some Typical Advances in the Synthetic Applications of Allenes

5. Electrophilic Addition and Cyclization Reactions of Allenes

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