Mononuclear Cu(ii) and Zn(ii) complexes with a simple diamine ligand: synthesis, structure, phosphodiester binding and DNA cleavage studies-Reference-Cited by-同舟云学术

Mononuclear Cu(ii) and Zn(ii) complexes with a simple diamine ligand: synthesis, structure, phosphodiester binding and DNA cleavage studies

Published:2015 Issue:29 Volume:5 Page:22405-22418
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Sureshbabu Popuri¹²³⁴,Tjakraatmadja A. A. J. Sudarga⁵⁶⁷,Hanmandlu Chittepu¹²³⁴,Elavarasan K.¹²³⁴,Kulak Nora⁵⁶⁷,Sabiah Shahulhameed¹²³⁴

Affiliation:

1. Department of Chemistry

2. Pondicherry University

3. Pondicherry-605 014

4. India

5. Institute of Chemistry and Biochemistry

6. Freie Universtität Berlin

7. Germany

Abstract

Mononuclear Cu(ii) and Zn(ii) complexes with simple 1,2-diaminocylohexane were synthesized. They interact with phosphodiesters and CT-DNA. Cu(ii) complex with ascorbate efficiently cleaves supercoiled DNA up to Form III at 25 µM under oxidative pathway.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA15717F

Reference91 articles.

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3. Oxidative and hydrolytic DNA cleavage by Cu(II) complexes of salicylidene tyrosine schiff base and 1,10 phenanthroline/bipyridine

4. DNA hydrolysis by inorganic catalysts

5. Zn2+ dependent DNA binders based on terminally modified peptide nucleic acids

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