Group 4 permethylindenyl constrained geometry complexes for ethylene polymerisation catalysis-Reference-Cited by-同舟云学术

Group 4 permethylindenyl constrained geometry complexes for ethylene polymerisation catalysis

Published:2018 Issue:21 Volume:8 Page:5454-5461
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Williams Thomas J.¹²³⁴⁵^ORCID,Buffet Jean-Charles¹²³⁴⁵^ORCID,Turner Zoë R.¹²³⁴⁵^ORCID,O'Hare Dermot¹²³⁴⁵^ORCID

Affiliation:

1. Chemistry Research Laboratory

2. Department of Chemistry

3. University of Oxford

4. Oxford OX1 3TA

5. UK

Abstract

The synthesis and characterisation of six permethylindenyl constrained geometry complexes is reported. Slurry phase ethylene polymerisation studies demonstrate that activities increase with increasing electron donating character of the amido fragment.

Funder

SCG Chemicals

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY01374H

Reference38 articles.

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2. Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalyst