Circularly polarised luminescence in an RNA-based homochiral, self-repairing, coordination polymer hydrogel

Author:

El-Zubir Osama1ORCID,Martinez Pablo Rojas1,Dura Gema12,Al-Mahamad Lamia L.G.3,Pope Thomas1ORCID,Penfold Thomas J.1ORCID,Mackenzie Lewis E.4,Pal Robert4ORCID,Mosely Jackie4,Cucinotta Fabio1ORCID,McGarry Liam F.1ORCID,Horrocks Benjamin R.1ORCID,Houlton Andrew1ORCID

Affiliation:

1. Chemical Nanoscience Labs, Chemistry, School of Natural Sciences, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK

2. Departamento de Química Inorgánica, Orgánica y Bioquímica, Facultad de Ciencias y Tecnologías Químicas, UCLM, Spain

3. Department of Chemistry, College of Science, Mustansiriyah University, Baghdad, Iraq

4. Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, UK

Abstract

The aqueous equimolar reaction of Ag(i) ions with the thionucleoside enantiomer (−)6-thioguanosine, ((−)6tGH), yields a one-dimensional coordination polymer {Ag(−)tG}n, the self-assembly of which generates left-handed helical chains that display CPL.

Funder

Engineering and Physical Sciences Research Council

European Regional Development Fund

H2020 European Research Council

Biotechnology and Biological Sciences Research Council

Royal Society

Newcastle University

Ministry of Higher Education and Scientific Research

Mustansiriyah University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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