Harnessing the active site triad: merging hemilability, proton responsivity, and ligand-based redox-activity-Reference-Cited by-同舟云学术

Harnessing the active site triad: merging hemilability, proton responsivity, and ligand-based redox-activity

Published:2020 Issue:4 Volume:49 Page:960-965
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Baumgardner Douglas F.¹²³⁴^ORCID,Parks Wyatt E.¹²³⁴,Gilbertson John D.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Western Washington University

3. Bellingham

4. USA

Abstract

Metalloenzymes catalyze important reactions by managing the proton and electron flux at the active site. In synthetic systems; hemilability, proton responsivity, and ligand-based redox-activity can be utilized as a bridge to harness this reactivity.

Funder

National Institutes of Health

Camille and Henry Dreyfus Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04470A

Reference76 articles.

1. V. Smil , Enriching the Earth: Fritz Haber, Carl Bosch, and the Transformation of World Food Production , MIT Press , Cambridge, Mass , 2001

2. Role of the Tyr-Cys Cross-link to the Active Site Properties of Galactose Oxidase

3. Nickel Superoxide Dismutase Structure and Mechanism

4. Proton-Coupled Electron Flow in Protein Redox Machines

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