Structural change of NaO1/2–WO3–NbO5/2–LaO3/2–PO5/2 glass induced by electrochemical substitution of sodium ions with protons

Author:

Ishiyama Tomohiro12345,Yamaguchi Takuya12345,Nishii Junji6785,Yamashita Toshiharu9105,Kawazoe Hiroshi9105,Kuwata Naoaki1112135,Kawamura Junichi1112135,Omata Takahisa12345

Affiliation:

1. Division of Materials and Manufacturing Science

2. Graduate School of Engineering

3. Osaka University

4. Suita 565–0871

5. Japan

6. Research Institute for Electronic Science

7. Hokkaido University

8. Sapporo 001-0021

9. Kawazoe Frontier Technologies Corp.

10. Yokohama 247-0014

11. Institute of Multidisciplinary Research for Advanced Materials

12. IMRAM Tohoku University

13. Sendai 980-8577

Abstract

Fragments of phosphate chains in 1W-glass are induced by electrochemical substitution of Na+ ions with H+ (APS), despite the total number of modifier cations being unaffected by APS.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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