Direct detection of spin polarization in photoinduced charge transfer through a chiral bridge

Author:

Privitera Alberto12ORCID,Macaluso Emilio34ORCID,Chiesa Alessandro34ORCID,Gabbani Alessio5ORCID,Faccio Davide6ORCID,Giuri Demetra6ORCID,Briganti Matteo2ORCID,Giaconi Niccolò27ORCID,Santanni Fabio2ORCID,Jarmouni Nabila5,Poggini Lorenzo8ORCID,Mannini Matteo2ORCID,Chiesa Mario1ORCID,Tomasini Claudia6ORCID,Pineider Francesco5ORCID,Salvadori Enrico1ORCID,Carretta Stefano34ORCID,Sessoli Roberta2ORCID

Affiliation:

1. Department of Chemistry and NIS Centre, University of Torino, Via Giuria 7, Torino, I-10125, Italy

2. Department of Chemistry “U. Schiff” (DICUS), University of Florence & UdR INSTM Firenze, Via della Lastruccia 3-13, Sesto Fiorentino, I-50019, Italy

3. Department of Mathematical, Physical and Computer Sciences, University of Parma & UdR INSTM, I-43124, Parma, Italy

4. INFN–Sezione di Milano-Bicocca, gruppo collegato di Parma, I-43124 Parma, Italy

5. Department of Chemistry and Industrial Chemistry, University of Pisa & UdR INSTM Pisa, Via Moruzzi 13, Pisa, I-56124, Italy

6. Department of Chemistry “Giacomo Ciamician”, University of Bologna, Via Selmi 2, Bologna, I-40126, Italy

7. Department of Industrial Engineering (DIEF), University of Florence & UdR INSTM Firenze, Via Santa Marta 3, Firenze, I-50139, Italy

8. CNR-ICCOM, Via Madonna del Piano 10, Sesto Fiorentino, I-50019, Italy

Abstract

Our work provides a first attempt to directly detect the spin polarisation of Chiral-Induced Spin Selectivity (CISS) effect by studying the photoinduced electron transfer in a CdSe Quantum Dot-chiral bridge-fullerene derivative (QD–χ–C60) system.

Funder

Fondazione Cariparma

Horizon 2020 Framework Programme

Ministero dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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