Reaction of N-heterocyclic carbenes with 13-vertex closo-carboranes: synthesis and structural characterization of zwitterionic salts of 13-vertex nido-carboranes-Reference-Cited by-同舟云学术

Reaction of N-heterocyclic carbenes with 13-vertex closo-carboranes: synthesis and structural characterization of zwitterionic salts of 13-vertex nido-carboranes

Published:2015 Issue:1 Volume:2 Page:55-59
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zheng Fangrui¹²³⁴⁵,Xie Zuowei¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Center of Novel Functional Materials and State Key Laboratory of Synthetic Chemistry

3. The Chinese University of Hong Kong

4. Hong Kong

5. China

Abstract

13-Vertexcloso-carboranes and N-heterocyclic carbenes undergo a fast acid–base reaction to generate intermediates that are slowly converted to the final products.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/QO/C4QO00287C

Reference35 articles.

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4. Group 4 metallocenes incorporating constrained-geometry carboranyl ligands

5. Constrained-geometry ruthenium carboranyl complexes and their unique chemical properties

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