Breaking the bottleneck: stilbene as a model compound for optimizing 6π e− photocyclization efficiency
Author:
Affiliation:
1. School of Polymer Science and Polymer Engineering
2. The University of Akron
3. Akron
4. USA
5. Department of Chemistry
6. Materials and Manufacturing Directorate
7. Air Force Research Laboratory
8. WPAFB
9. ARCTOS Technology Solutions
Abstract
TEMPO is more effective than iodine in free-radical mediated, photochemical oxidative cyclization of stilbenes at elevated concentrations.
Funder
Air Force Research Laboratory
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/RA/D0RA10619D
Reference34 articles.
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2. The Conservation of Orbital Symmetry
3. What Happens during the Picosecond Lifetime of 2A1 Cyclohexa-1,3-diene? A CAS-SCF Study of the Cyclohexadiene/Hexatriene Photochemical Interconversion
4. Is the nonradiative decay of S1 cis-stilbene due to the dihydrophenanthrene isomerization channel? Suggestive evidence from photophysical measurements on 1,2-diphenylcycloalkenes
5. The Photochemistry of Stilbenoid Compounds and Their Role in Materials Technology
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1. Synthesis of V-shaped Thiophene Based Rotor-Stilbene: Substituent Dependent Aggregation and Photophysical Properties;Journal of Fluorescence;2024-02-06
2. Photochemical behavior of diheteroarylethenes and photochromism;Photochemistry of Heterocycles;2023
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